Organosilanes in Radical Chemistry

Organosilanes in Radical Chemistry, 9780471498704 (047149870X), John Wiley & Sons, 2004

A large number of papers dealing with silyl radicals, dating back to the late 1940s, have been published. To my knowledge, there are no books on this subject. Several reviews and book chapters on silyl radicals have appeared from time to time on specific aspects. This book focuses on the recent literature of silyl radicals in the liquid phase. However, some related gas-phase data of pivotal species such as the H3Si: and Me3Si: radicals are taken into consideration when necessary. In the last decade, silyl radicals have thoroughly penetrated areas as diverse as organic synthesis and material sciences, and the eight chapters in this book survey the most exciting aspects of their chemistry.

In recent years silicon-centered radicals have played an important role in organic synthesis, polymer chemistry and material sciences. The aim of this book is to offer for the first time a description of silyl radicals within an interdisciplinary context, connecting structural characteristics and chemical properties to their application in different areas of chemistry.

The first time different aspects of silyl radicals have been brought together
Excellent reference tool for experienced practitioners of radical and/or silicon chemistry
Presents various aspects of these intermediates in an original, comprehensive fashion

This book is essential for anyone working in free radical and/or silicon chemistry as well as for those who want to approach these fields for the first time.

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