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A Guide To Chalcogen-nitrogen Chemistry

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The quintessential chalcogen-nitrogen compound tetrasulfur tetranitride, S4N4, was first detected by Gregory in 1835 just ten years after the discovery of benzene. Its unusual structure, like that of benzene, was not elucidated for over 100 years. The application of diffraction techniques revealed the unusual cage arrangement with two weak cross-ring sulfur–sulfur interactions. The details of the electronic structure of this fascinating molecule are still a matter of debate today.

Pioneering work in Germany, especially by the groups of Becke-Goehring, Weiss and Glemser, in the middle of the previous century uncovered a rich chemistry for inorganic sulfur–nitrogen systems. Their early efforts were notable because of the unavailability of many modern physical techniques for structural characterization that are commonplace today. The book by Goehring entitled “Ergebnisse und Probleme der Chemie der Schewfelstickstoffverbindungen” deserves special mention for the stimulus that it provided to subsequent workers in the field.
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